A self-cleaning glass keeps itself spotless underwater

Microscopic pancakes on its surface stop dirt from sticking

A new kind of glass can keep itself clean underwater. The key is microscopic pancake-shaped structures that let liquid flow between them.

ES3N/iStockphoto

 

Imagine a surface you never had to clean — because it never gets dirty. It stays spotless, resisting dirt and oil. New research finds that the secret to such a long-lasting, scrub-free shine might be microscopic pancakes.  

Some self-cleaning surfaces already exist. Stores don’t yet sell these self-cleaning clothes, kitchen utensils and windows, to name a few. But scientists are working on them. Up close, you’d see that microscopic pillars or columns cover the surface of many of these. A material coating those tiny structures repels oil and dirt. The narrow pillar tops also give grime less area to stick. That helps gunk slide off.

But micro-pillars are far from ideal. The tall, thin columns easily bend, snap and topple. Over time, dirt and oil can collect around damaged pillars. That buildup is hard to dislodge without some form of cleaning. And if the surface is glass, those busted pillars cause even more trouble. Bent and broken bits — and stuck gunk — interfere with light passing through the glass. That can blur or distort images viewed through them.

To address these issues, scientists in Norway took a new approach. Instead of pillars, they used shorter, squatter pancake shapes. And so far, those pancakes seem to do the trick. A window tested in the ocean has stayed clean and clear for more than a year.

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Scanning electron microscope images show the microscopic “pancakes” on the self-cleaning glass surface. Each pancake is roughly five micronmeters across. That’s about the size of one red blood cell, or one-twentieth the width of a human hair.
Akhtar et al/American Chemical Society (ACS)

“Unlike pillars, water moves freely between our pancake microstructures,” says Bodil Holst. She’s a physicist at the University of Bergen in Norway. With taller pillars, more water molecules get slowed down as they try to pass the structures. Water flows more easily around the shorter structures. Underwater, that liquid flow keeps dirt from sticking. In fact, that provides the self-cleaning, meaning the surface doesn’t need a dirt-repelling coating. 

Their stout shape also makes the pancakes more durable. Imagine two pieces of chalk: one long and thin, the other short and flat, Holst says. “It would require a lot more effort to break a short piece of chalk,” she points out. “In the same way, it takes a lot more effort to break microscopic pancakes compared to pillars.”  

In her team’s tests, those pancakes have remained firmly in place and in shape. Holst’s group described its findings December 12, 2018, in Nano Letters.

A clear problem

The pancake project arose from a real-world problem. “The company we work with uses light-detecting sensors to test water quality,” explains Naureen Akhtar. She is a physicist who works with Holst at the University of Bergen. “The problem is, the sensor sits behind a window that gets dirty far too quickly. Sometimes it’s soiled after only one week.”

Cleaning the window so often takes a lot of costly time and effort. So the company wanted a long-lasting, self-cleaning window. That’s when Akhtar and Holst’s team came up with their innovation: pancaking the surface.

Once they’d created their new glass, they were ready to test it in the ocean. To do that, they replaced the old, easily soiled glass in front of the sensors with the pancake-studded glass.

The researchers — and the company — have been pleased with the results. In some cases, they extended the time between window cleans from weekly to yearly, Akhtar says.

Their glass also performed well in the lab. In one test, a clean glass window was dunked in an oily mixture for 46 hours. It ended up absolutely covered in gunk. The researchers repeated the test on a glass window whose surface was coated with micropancakes. That one stayed completely clean.

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Sitting in an oily mixture left the glass on the left gunky and clouded. But the self-cleaning window on the right stayed completely clean, even after 46 hours.
Akhtar et al/American Chemical Society (ACS)

“Something like this would be extremely useful in areas that are remote or hard to access,” says Gareth McKinley at the Massachusetts Institute of Technology in Cambridge. He’s a mechanical engineer who did not work on the new glass. “It’s simply too hard,” he notes, “to send a window cleaner into some locations underground or underwater — human or robot.”

Akhtar thinks the new technology could be useful for self-cleaning windows on ships and ocean-exploration vessels. It might even keep algae or bacteria from growing on the glass lenses of underwater cameras and sensors. This kind of buildup, called biofouling, can interfere with how the lenses work. 

The micropancakes still have room for improvement, though. McKinley notes that the new surface slowed down the dirtying of the glass but didn’t prevent it completely. Holst’s team hopes that future versions of their product will work even better.  

This is one in a series presenting news on technology and innovation, made possible with generous support from the Lemelson Foundation.

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